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Nicholas H. Evans, Dr. Christopher J. Serpell, Nicholas G. White and Prof. Paul D. Beer A 1,2,3,4,5-Pentaphenylferrocene-Stoppered Rotaxane Capable of Electrochemical Anion Recognition Chemistry - A European Journal 17

Article first published online: 26 SEP 2011 | DOI: 10.1002/chem.201101811

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Topologically constrained host cavity for sensing chloride ions: Chloride anion templated synthesis of an electrochemical, anion sensory, interlocked host system, prepared by the integration of redox-active 1,2,3,4,5-pentaphenylferrocene stopper groups into the structure of a rotaxane (see picture), is described. A characteristic electrochemical response for chloride binding by the rotaxane is observed, attributed to the topologically constrained cavity of the interlocked molecule.

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