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Ye Bi , Yun-Nan Guo, Lang Zhao, Yang Guo, Shuang-Yan Lin, Shang-Da Jiang, Prof.Dr. Jinkui Tang, Prof. Dr. Bing-Wu Wang and Prof. Dr. Song Gao Capping Ligand Perturbed Slow Magnetic Relaxation in Dysprosium Single-Ion Magnets Chemistry - A European Journal 17

Version of Record online: 20 SEP 2011 | DOI: 10.1002/chem.201101838

Thumbnail image of graphical abstract

Coordination-sphere distortion due to different capping ligands in square-antiprismatic single-ion magnets [Ln(TTA)3(LCAP)], quantified by the skew angle Φ, exhibit distinct magnetic relaxation rates (see picture; TTA = thenoyltrifluoroacetonate, LCAP=2,2′-bipyridine (green), 1,10-phenanthroline (blue); empty symbols refer to samples magnetically diluted with the analogous Y complex).

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