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Dr. Boris Kurscheid, Beate Neumann, Dr. Hans-Georg Stammler and Prof. Dr. Berthold Hoge Air-Stable Platinum and Palladium Complexes Featuring Bis[2,4-bis(trifluoromethyl)phenyl]phosphinous Acid Ligands Chemistry - A European Journal 17

Article first published online: 6 DEC 2011 | DOI: 10.1002/chem.201102347

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Walking in the air: Two phosphinous acid ligands bind to a square-planar platinum complex (see scheme). Removal of one proton affords anionic cis-configured complex 2. A second deprotonation is accompanied by rearrangement to the trans dianion 3.

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