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Dr. Qing-Hai Deng, Prof. Dr. Hubert Wadepohl and Prof. Dr. Lutz H. Gade The Synthesis of a New Class of Chiral Pincer Ligands and Their Applications in Enantioselective Catalytic Fluorinations and the Nozaki–Hiyama–Kishi Reaction Chemistry - A European Journal 17

Article first published online: 3 NOV 2011 | DOI: 10.1002/chem.201102375

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A pincer with a twist: A Wittig coupling is the key step in the modular synthesis of chiral pincer ligands 1 (boxmi). Their NiII complexes catalyze the enantioselective fluorination of oxindoles and cyclic β-ketoesters with extremely high enantioselectivity, whereas their use in Cr-catalyzed enantioselective Nozaki–Hiyama–Kishi reactions of aldehydes gave the corresponding alcohols.

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