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Dr. De-en Jiang Staple Fitness: A Concept To Understand and Predict the Structures of Thiolated Gold Nanoclusters Chemistry - A European Journal 17

Version of Record online: 20 SEP 2011 | DOI: 10.1002/chem.201102391

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Survival of the fittest: A profound connection has been found between the structures of thiolated gold clusters and the combinatorial problem of pairing up dots on a surface. The bridge is the concept of staple fitness: the fittest combination corresponds to the experimental structure. This connection has been demonstrated for both Au25(SR)18 and Au38(SR)24 (-SR being a thiolate group) and applied to predict a promising structure for the recently synthesized Au19(SR)13.

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