Dr. Yasuhiro Ishida, Hiroaki Sakata, Dr. Ammathnadu S. Achalkumar, Kuniyo Yamada, Dr. Yuki Matsuoka, Nobutaka Iwahashi, Dr. Sayaka Amano and Prof. Kazuhiko Saigo Guest-Responsive Covalent Frameworks by the Cross-Linking of Liquid-Crystalline Salts: Tuning of Lattice Flexibility by the Design of Polymerizable Units Chemistry - A European Journal 17
Solid-state hosts with covalent frameworks were obtained by the in situ cross-linking of liquid-crystalline salts composed of a polymerizable carboxylic acid and an enantiopure amino alcohol (see scheme). In response to the desorption and adsorption of the amino alcohol unit, the cross-linked polymers reversibly changed their structures. The dynamic properties of the cross-linked polymers could be tuned by the choice of cross-linking units.
Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf