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Dr. Yasuhiro Ishida, Hiroaki Sakata, Dr. Ammathnadu S. Achalkumar, Kuniyo Yamada, Dr. Yuki Matsuoka, Nobutaka Iwahashi, Dr. Sayaka Amano and Prof. Kazuhiko Saigo Guest-Responsive Covalent Frameworks by the Cross-Linking of Liquid-Crystalline Salts: Tuning of Lattice Flexibility by the Design of Polymerizable Units Chemistry - A European Journal 17

Version of Record online: 6 DEC 2011 | DOI: 10.1002/chem.201102422

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Solid-state hosts with covalent frameworks were obtained by the in situ cross-linking of liquid-crystalline salts composed of a polymerizable carboxylic acid and an enantiopure amino alcohol (see scheme). In response to the desorption and adsorption of the amino alcohol unit, the cross-linked polymers reversibly changed their structures. The dynamic properties of the cross-linked polymers could be tuned by the choice of cross-linking units.

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