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Joaquin Barjau, Dr. Jan Fleischhauer, Dr. Gregor Schnakenburg and Prof. Dr. Siegfried R. Waldvogel Installation of Amine Moieties into a Polycyclic Anodic Product Derived from 2,4-Dimethylphenol Chemistry - A European Journal 17

Version of Record online: 24 NOV 2011 | DOI: 10.1002/chem.201102722

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Pure resolution: Starting from 2,4-dimethylphenol, its polycyclic dehydrotetramer is readily obtainable by anodic treatment. Modification with optically pure amines allows the separation of the generated diastereoisomers, which equilibrate between the hemiketal and keto form (see scheme).

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