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Jordi Esteban, Prof. Eliseo Ruiz, Dr. Mercé Font-Bardia, Dr. Teresa Calvet and Prof. Albert Escuer Triangular Nickel Complexes Derived from 2-Pyridylcyanoxime: An Approach to the Magnetic Properties of the [Ni3(μ3-OH){pyC(R)NO}3]2+ Core Chemistry - A European Journal 18

Article first published online: 15 FEB 2012 | DOI: 10.1002/chem.201102987

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Triangulation: Experimental and DFT calculations reveal the magnetic response of triangular NiII–oximato systems (see figure). The magnetic properties of several Ni3, Ni4 and Ni5 complexes with topologies based on isolated, edge- or vertex-sharing triangular μ3-OR nickel–oximate units have been elucidated and compared with analogous copper or manganese systems.

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