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Dr. Benjamin J. Slater, Dr. E. Stephen Davies, Dr. Stephen P. Argent, Dr. Harriott Nowell, Dr. William Lewis, Prof. Dr. Alexander J. Blake and Prof. Dr. Neil R. Champness A Perylene Diimide Rotaxane: Synthesis, Structure and Electrochemically Driven De-Threading Chemistry - A European Journal 17

Version of Record online: 1 DEC 2011 | DOI: 10.1002/chem.201103090

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Perylene diimides make excellent building blocks for the formation of [2]-rotaxanes. The rich electrochemistry of the perylene-based recognition site facilitates a pathway to different oxidation states and properties and allows a mechanism for electrochemically driven de-treading of the interlocked species (see figure).

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