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Dr. James McNulty, Kunal Keskar and Dr. Ramesh Vemula The First Well-Defined Silver(I)-Complex-Catalyzed Cycloaddition of Azides onto Terminal Alkynes at Room Temperature Chemistry - A European Journal 17

Article first published online: 28 NOV 2011 | DOI: 10.1002/chem.201103244

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Silver(I)-catalyzed click chemistry: Substituted 1,2,3-triazoles are versatile intermediates with an expanding array of applications. The discovery and application of a general AgI-catalyzed azide–alkyne cycloaddition reaction (AAC) leading to 1,2,3-triazoles is reported. The synthesis of a stable, well-defined AgI complex of type [AgI(L2)(OAc)] is described, along with the unprecedented ability of this complex to promote the general Ag-AAC at room temperature (see scheme).

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