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Dr. Pascal Roy, Andreas Schaate, Prof. Dr. Peter Behrens and Prof. Dr. Adelheid Godt Post-Synthetic Modification of Zr-Metal–Organic Frameworks through Cycloaddition Reactions Chemistry - A European Journal 18

Version of Record online: 16 APR 2012 | DOI: 10.1002/chem.201103288

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Modifying and disassembling MOFs: Porous interpenetrated Zr-organic frameworks (PIZOFs) with large pores have been post-synthetically modified through 1,3-dipolar cycloaddition and Diels–Alder reactions (see scheme, left). Additionally, a simple procedure is reported for the disassembly of the hydrolytically very stable UiO-66- and PIZOF-type Zr-based MOFs for analytical purposes (see scheme, right).

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