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Björn Hildebrandt, Dr. Stephan Raub, Prof. Dr. Walter Frank and Prof. Dr. Christian Ganter Expanding the Chemistry of Cationic N-Heterocyclic Carbenes: Alternative Synthesis, Reactivity, and Coordination Chemistry Chemistry - A European Journal 18

Version of Record online: 4 APR 2012 | DOI: 10.1002/chem.201103707

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Widening our knowledge: The properties and reactions of the cationic N-heterocyclic carbene A are reported (see scheme), including the formation of transition-metal complexes. X-ray structural, electrochemical, and vibrational data indicate that A is an electron-poor carbene. Two additional synthetic approaches to the complexes of ligand A are presented.

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