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Dr. Daniel Himmel, Dipl.-Chem. Sascha K. Goll, Prof. Dr. Ivo Leito and Prof. Dr. Ingo Krossing Bulk Gas-Phase Acidity Chemistry - A European Journal 18

Version of Record online: 21 JUN 2012 | DOI: 10.1002/chem.201104025

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Brønsted “gacids”: Brønsted acidity in the gas phase has been systematically extended from the established gas-phase acidity values to the pressure-dependent bulk acidity. Analogies to protolysis in solution are illustrated on the basis of a unified pHabs scale. For most gaseous acids, the pressure-dependent speciation of ions in the gas phase must be considered (see figure) to obtain meaningful thermodynamic acidities of bulk gases.

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