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Dr. Henning S. G. Beckmann, Dipl.-Chem. Andrea Niederwieser, Prof. Dr. Manfred Wiessler and Prof. Dr. Valentin Wittmann Preparation of Carbohydrate Arrays by Using Diels–Alder Reactions with Inverse Electron Demand Chemistry - A European Journal 18

Article first published online: 18 APR 2012 | DOI: 10.1002/chem.201200382

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Served on a plate: Chemoselective immobilization of synthetic dienophile–carbohydrate conjugates has been achieved on tetrazine-derivatized glass slides by employing Diels–Alder reactions with inverse electron demand. By using a bifunctional linker, unmodified reducing oligosaccharides can also be selectively tagged with a dienophile and subsequently immobilized (see figure).

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