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Daniel Winkelhaus, Beate Neumann, Dr. Hans-Georg Stammler, Dr. Raphael J. F. Berger, Dr. Yuri V. Vishnevskiy and Prof. Dr. Norbert W. Mitzel Inherent Stability Limits of Intramolecular Boron Nitrogen Lewis Acid–Base Pairs Chemistry - A European Journal 18

Article first published online: 15 JUN 2012 | DOI: 10.1002/chem.201200442

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Two roads diverged: Two different reaction pathways in the hydroboration of allylamines R2NCH2CHCH2 with (C6F5)2BH lead to the expected heterocycles with B[BOND]N bonds for small R substituents, but to hydride abstraction and evolution of dihydrogen for R=iPr (see scheme).

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