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Dipl.-Chem. Anne Kraft, Dr. Nils Trapp, Dr. Daniel Himmel, Dipl.-Chem. Hannes Böhrer, Dipl.-Chem. Peter Schlüter, Dr. Harald Scherer and Prof. Dr. Ingo Krossing Synthesis, Characterization, and Application of Two Al(ORF)3 Lewis Superacids Chemistry - A European Journal 18

Article first published online: 26 JUN 2012 | DOI: 10.1002/chem.201200448

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A super method! The synthesis of the donor-free Lewis superacids Al(ORF)3 with ORF=OC(CF3)3 (1) and OC(C5F10)C6F5 (2), as well as stabilization of 1 with the very weak Lewis bases PhF, 1,2-F2C6H4, and SO2, is reported (see figure). Applications of 1 and 2 in bond heterolysis reactions with Cl[BOND]CPh3 giving the trityl cation and the respective weakly coordinating anion [ClAl(ORF)3] are also described.

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