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Dr. Zhi-Ming Zhang, Dr. Shuang Yao, Dr. Yang-Guang Li, Xin-Bao Han, Prof. Zhong-Min Su, Zhi-Shu Wang and Prof. En-Bo Wang Inorganic Crown Ethers: Sulfate-Based Preyssler Polyoxometalates Chemistry - A European Journal 18

Version of Record online: 26 JUN 2012 | DOI: 10.1002/chem.201200555

Thumbnail image of graphical abstract

A tungsten crown: The {SO4} units were introduced into the {W30} crown, resulting in a new Preyssler polyoxoanion {S5W30} with position-specific, guest, K+ or Na+ ions in its geometrical center. The as-prepared polyoxoanion exhibits an interesting ion-selective encapsulation of K+ and Na+ (see figure).

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