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Elizabeth A. Jacobs, Anna Fuller, Simon J. Coles, Garth A. Jones, Graham J. Tizzard, Joseph A. Wright and Simon J. Lancaster Synthesis and Structure of Amido- and Imido(pentafluorophenyl)borane Zirconocene and Hafnocene Complexes: N[BOND]H and B[BOND]H Activation Chemistry - A European Journal 18

Article first published online: 12 JUN 2012 | DOI: 10.1002/chem.201200704

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Chelate bonding: Lithium amidopentafluorophenylboranes react with electrophilic Group 4 metallocenes through N[BOND]H and B[BOND]H activation to give novel amidoborane and imidoborane complexes, which are bound in chelate fashion with a β-B-agostic interaction (see scheme).

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