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Bing Zheng, Shuo-Ning Li, Jian-You Mao, Bo Wang, Dr. Qing-Hua Bian, Dr. Shang-Zhong Liu, Dr. Jiang-Chun Zhong, Dr. Hong-Chao Guo and Dr. Min Wang Highly Enantioselective Addition of 1,3-Diynes to Aldehydes Catalyzed by a Zinc–Amino Alcohol Complex Chemistry - A European Journal 18

Version of Record online: 19 JUN 2012 | DOI: 10.1002/chem.201200728

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Asymmetric catalysis: A highly enantioselective and efficient procedure for the amino alcohol–zinc-catalyzed addition of 1,3-diynes to various aromatic, α,β-unsaturated, and aliphatic aldehydes has been developed. The present catalytic system was successfully applied in the concise synthesis of natural products such as (S)-strongylodiols A and B (see scheme).

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