E-mail a Wiley Online Library Link

Dipl.-Chem. Crispin Lichtenberg, Dr. Thomas P. Spaniol, Dr. Lionel Perrin, Prof. Dr. Laurent Maron and Prof. Dr. Jun Okuda Reversible 1,4-Insertion of Pyridine Into a Highly Polar Metal–Carbon Bond: Effect of the Second Metal Chemistry - A European Journal 18

Article first published online: 19 APR 2012 | DOI: 10.1002/chem.201200808

Thumbnail image of graphical abstract

Highly polar allylpotassium reacts with pyridine in a reversible 1,4-insertion to give an unstable N-metalated dihydropyridine (DHP). The N-metalated DHP can be stabilized by conversion into the corresponding potassium zincate or magnesate maintaining the reversible character of the insertion reaction (see scheme).

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field