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Dr. Jabor Rabeah, Prof. Dr. Reinhard Stößer, Dr. Haijun Jiao, Prof. Dr. Sergey I. Troyanov, Dr. Jörg Radnik, Dr. Helmut Dwelk, Prof. Dr. Manfred Meisel and Prof. Dr. Angelika Brückner Tuning the Electronic and Spin Complexity in Organic–Inorganic Molecular Hybrid Compounds Chemistry - A European Journal 18

Version of Record online: 19 APR 2012 | DOI: 10.1002/chem.201200931

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Caught by the cage: New vanadium phosphonate cages with a fluoride template inside and charge-compensating transition-metal cations outside were prepared in a simple way. The charge and ligand sphere of the cation govern its interaction with the cage and can be used to modify the magnetic and redox properties of the cage, which also depend on the anionic template (see figure).

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