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Dr. Tadao Takada, Yumiko Otsuka, Dr. Mitsunobu Nakamura and Prof. Dr. Kazushige Yamana Molecular Arrangement and Assembly Guided by Hydrophobic Cavities inside DNA Chemistry - A European Journal 18

Version of Record online: 19 JUN 2012 | DOI: 10.1002/chem.201201469

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Filling the gaps: Molecular arrangement and assembly within π-stacked arrays of DNA were achieved by utilizing artificial hydrophobic cavities to accommodate ligand molecules (perylenediimide (PDI); see scheme). Site-specific binding of PDI to the cavity, formation of stacked PDI molecules in the cavity, and binding of two PDIs to different binding cavities were characterized by monitoring spectroscopic characteristics of the PDI molecules.

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