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Nazli Jalalian, Dr. Tue B. Petersen and Prof. Berit Olofsson Metal-Free Arylation of Oxygen Nucleophiles with Diaryliodonium Salts Chemistry - A European Journal 18

Version of Record online: 27 SEP 2012 | DOI: 10.1002/chem.201201645

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Believe the hype! Phenols, carboxylic acids, and sulfonic acids are efficiently arylated with diaryliodonium salts (see scheme). The reaction conditions are mild, metal free, and avoid the use of halogenated solvents, additives, and excess reagents. The products are obtained in good to excellent yields in short reaction times. Unsymmetric salts can be chemoselectively utilized to obtain products with hitherto unreported levels of steric hindrance.

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