Toshiki Nagamachi, Dr. Youhei Takeda, Kazuhisa Nakayama and Prof. Dr. Satoshi Minakata Selective Functionalization of Fullerenes with N,N-Dihalosulfonamides as an N1 Unit: Versatile Syntheses of Azafulleroids and Aziridinofullerenes and their Application to Photovoltaic Cells Chemistry - A European Journal 18
Full steam ahead: Highly selective and versatile syntheses of azafulleroids and aziridinofullerenes from C60, which utilize N,N-dihalosulfonamides as an N1 source, were developed. Photophysical, electrochemical, and thermal properties of the iminofullerenes were measured, and photovoltaic cells based on these compounds were fabricated. The power conversion efficiencies (PCEs) of the devices show moderate values ranging from 1.33 to 2.35 % (see scheme).
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