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Dr. Jürgen Rotzler, Sylvie Drayss, Dr. Oliver Hampe, Dr. Daniel Häussinger and Prof. Dr. Marcel Mayor Molecular Daisy Chains: Synthesis and Aggregation Studies of an Amphiphilic Molecular Rod Chemistry - A European Journal 19

Version of Record online: 7 JAN 2013 | DOI: 10.1002/chem.201202498

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Oligomeric daisy chains: A water-soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers (see figure). This hermaphroditic compound forms [c2]daisy chains in polar solvents over a wide range of concentrations. Furthermore, evidence for the formation of larger, mechanically interlinked oligomers above the critical aggregation concentration has been obtained.

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