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Tao Zhang, Xunjin Zhu, Wai-Kwok Wong, Hoi-Lam Tam and Wai-Yeung Wong Light-Harvesting Ytterbium(III)–Porphyrinate–BODIPY Conjugates: Synthesis, Excitation-Energy Transfer, and Two-Photon-Induced Near-Infrared-Emission Studies Chemistry - A European Journal 19

Article first published online: 20 NOV 2012 | DOI: 10.1002/chem.201202613

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So NIR and yet: Ytterbium–porphyrinate complexes that were conjugated with BODIPY dyes were prepared and fully characterized (see figure). Their photophysical properties, in particular the NIR emissions that corresponded to the YbIII ion, as well as the energy transfer between the donors and the acceptors, were investigated in detail. Moreover, the nonlinear (two-photon-absorption) properties of these complexes were examined.

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