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Dr. Sonia Martínez-Salvador, Prof. Dr. Juan Forniés, Dr. Antonio Martín, Dr. Babil Menjón and Dr. Isabel Usón Stepwise Degradation of Trifluoromethyl Platinum(II) Compounds Chemistry - A European Journal 19

Article first published online: 20 NOV 2012 | DOI: 10.1002/chem.201202648

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Step by step: Selective and stepwise degradation of CF3 groups in the homoleptic organoplatinum(II) derivative [NBu4]2[Pt(CF3)4] can be achieved by using increasingly harsher acidic conditions (Brønsted acids: H2O or HCl, see scheme). Indirect evidence for the intermediacy of the highly electrophilic [Pt][DOUBLE BOND]CF2 species has been attained through the isolation and structural characterization of a donor (L)-stabilized [Pt][DOUBLE BOND]CF2L compound.

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