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Hadrien Heuclin, Dr. Xavier F. Le Goff and Dr. Nicolas Mézailles Mixed (P[DOUBLE BOND]S/P[DOUBLE BOND]O)-Stabilized Geminal Dianion: Facile Diastereoselective Intramolecular C[BOND]H Activations by a Related Ruthenium–Carbene Complex Chemistry - A European Journal 18

Version of Record online: 7 NOV 2012 | DOI: 10.1002/chem.201202680

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P[DOUBLE BOND]S, you're a gem: A new type of geminal dianion that combines P[DOUBLE BOND]O and P[DOUBLE BOND]S moieties allows the synthesis of a highly reactive Ru–carbene complex (see scheme). This complex exhibits a diastereospecific intramolecular C[BOND]H activation of the ligand.

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