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Dr. Atanu Jana, Dr. Masatoshi Ishida, Kyuju Kwak, Young Mo Sung, Dong Sub Kim, Dr. Vincent M. Lynch, Prof. Dr. Dongil Lee, Prof. Dr. Dongho Kim and Prof. Dr. Jonathan L. Sessler Comparative Electrochemical and Photophysical Studies of Tetrathiafulvalene-Annulated Porphyrins and Their ZnII Complexes: The Effect of Metalation and Structural Variation Chemistry - A European Journal 19

Version of Record online: 23 NOV 2012 | DOI: 10.1002/chem.201202727

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TTF to transfer: A series of tetrathiafulvalene (TTF)-annulated porphyrins, along with their corresponding ZnII complexes, have been synthesized and subjected to detailed electrochemical and photophysical analysis (see figure). It was found that the synthetic addition of TTF moieties to the porphyrin core makes the resulting macrocycle more susceptible to charge-transfer processes.

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