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Dr. Michael Jäger , Dr. Helmar Görls, Dr. Wolfgang Günther and Prof. Dr. Ulrich S. Schubert  Pd-Catalyzed Ring Assembly by Vinylation and Intramolecular Heck Coupling: A Versatile Strategy Towards Functionalized Azadibenzocyclooctynes Chemistry - A European Journal 19

Version of Record online: 19 DEC 2012 | DOI: 10.1002/chem.201202790

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Cascade ring assembly: A modular route for construction of the azocine scaffold was developed that allows efficient large-scale preparation in 1–2 steps. The novel N-benzoyl octyne was prepared and isolated by simple crystallization, and displays high reactivity in a typical copper-free click reaction (see scheme).

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