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Dr. Tobias Ankner, Dr. Casey C. Cosner and Prof. Dr. Paul Helquist Palladium- and Nickel-Catalyzed Alkenylation of Enolates Chemistry - A European Journal 19

Version of Record online: 16 JAN 2013 | DOI: 10.1002/chem.201202798

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Close coupling: Coupling reactions of enolates with alkenyl halides are most commonly performed with various palladium catalysts and to a lesser extent with nickel catalysts (see scheme). Intra- and intermolecular, and enantioselective versions of these reactions have been developed and employed in a number of syntheses of natural products and other compounds of interest.

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