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Dr. Matthew L. Reback, M. Sc. Bojana Ginovska-Pangovska, Dr. Ming-Hsun Ho, Dr. Avijita Jain, Dr. Thomas C. Squier, Dr. Simone Raugei, Dr. John A. S. Roberts and Dr. Wendy J. Shaw The Role of a Dipeptide Outer-Coordination Sphere on H2-Production Catalysts: Influence on Catalytic Rates and Electron Transfer Chemistry - A European Journal 19

Version of Record online: 11 DEC 2012 | DOI: 10.1002/chem.201202849

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Peptide-like scaffold enhancements: [Ni(PPh2NPh-dipeptide2)2]2+ electrocatalysts containing dipeptides in the outer-coordination sphere (such as depicted) show an impact on rate and overpotential. Amide functional groups enhance the rate modestly, while polar and aromatic groups do not impact catalysis. This work shows the impact that an outer-coordination sphere can have on a molecular catalyst system.

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