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Ross J. Ellis, Yannick Meridiano, Renato Chiarizia, Laurence Berthon, Julie Muller, Laurent Couston and Mark R. Antonio Periodic Behavior of Lanthanide Coordination within Reverse Micelles Chemistry - A European Journal 19

Version of Record online: 7 JAN 2013 | DOI: 10.1002/chem.201202880

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The combination of structural insights obtained from the ion-, molecule-, and aggregate-centric perspectives provides a unified view of the core architectures of reverse micelles formed in water-in-oil systems with an extractant of practicality in separation science (see figure). The effects of aqueous media on organic microemulsions are not subtle, showing variations of mono- and bidentate nitrate coordination to LnIII and hydration as well as mesoscale variations of micellar morphology.

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