E-mail a Wiley Online Library Link

Yuko Wada, Kenta Iyoki, Dr. Ayae Sugawara-Narutaki, Prof. Dr. Tatsuya Okubo and Prof. Dr. Atsushi Shimojima Diol-Linked Microporous Networks of Cubic Siloxane Cages Chemistry - A European Journal 19

Article first published online: 30 NOV 2012 | DOI: 10.1002/chem.201202883

Thumbnail image of graphical abstract

Out of the cage: A new class of inorganic–organic hybrid microporous materials has been synthesized by treating octa(hydridosilsesquioxane) (H8Si8O12; see figure, D4R=double-four-ring structure) with various diols, including 1,3-propanediol (PD), 1,4-cyclohexanediol (CHD), and 1,3-adamantanediol (AD). The AD-linked product is highly stable against hydrolysis, possibly owing to the higher steric hindrance and the high hydrophobicity of AD links.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

Choose captcha format: Image or Audio. Click here if you need help.