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Dr. Michael J. Page, Wei Y. Lu, Rebecca C. Poulten, Dr. Emma Carter, Dr. Andrés G. Algarra, Dr. Benson M. Kariuki, Prof. Stuart A. Macgregor, Dr. Mary F. Mahon, Prof. Kingsley J. Cavell, Dr. Damien M. Murphy and Prof. Michael K. Whittlesey Three-Coordinate Nickel(I) Complexes Stabilised by Six-, Seven- and Eight-Membered Ring N-Heterocyclic Carbenes: Synthesis, EPR/DFT Studies and Catalytic Activity Chemistry - A European Journal 19

Version of Record online: 4 JAN 2013 | DOI: 10.1002/chem.201202950

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Three of a kind: A series of three-coordinate NiI complexes stabilised by N-aryl substituted six-, seven- and eight-membered ring N-heterocyclic carbenes (see figure) have been prepared and characterised by a combination of X-ray crystallography, EPR spectroscopy and DFT calculations. The complexes are precursors for the Kumada cross-coupling of aryl chlorides and fluorides.

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