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Atsushi Yamamoto, Tetsuya Hasegawa, Tomoya Hamada, Tomofumi Hirukawa, Dr. Ichiro Hisaki, Prof. Dr. Mikiji Miyata and Dr. Norimitsu Tohnai Role-Allocated Combination of Two Types of Hydrogen Bonds towards Constructing a Breathing Diamondoid Porous Organic Salt Chemistry - A European Journal 19

Version of Record online: 10 JAN 2013 | DOI: 10.1002/chem.201202959

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Breathing architecture: A hierarchical design by using an organic salt combining charge-assisted hydrogen bonds and complementary neutral hydrogen bonds provides a flexible diamondoid porous organic salt (d-POS; see figure). The structure and fluorescence of the resultant d-POS are reversibly changed in response to guest desorption and adsorption, originating in the role-allocated association of the hydrogen bonds.

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