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Sabrina Freye, David M. Engelhard, Dr. Michael John and Prof. Dr. Guido H. Clever Counterion Dynamics in an Interpenetrated Coordination Cage Capable of Dissolving AgCl Chemistry - A European Journal 19

Article first published online: 19 DEC 2012 | DOI: 10.1002/chem.201203086

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Cleverly unlocked: The solvent- and temperature-dependent dynamic behavior of anions occupying the central and the two outer pockets of a self-assembled, interpenetrated double cage is presented. Addition of two equivalents of solid AgCl led to exchange of the BF4 ions in the outer pockets by chloride (see figure). NOE data shows that the allosteric binding is accompanied by compression along and torsion around the Pd4 axis.

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