Sabrina Freye, David M. Engelhard, Dr. Michael John and Prof. Dr. Guido H. Clever Counterion Dynamics in an Interpenetrated Coordination Cage Capable of Dissolving AgCl Chemistry - A European Journal 19
Cleverly unlocked: The solvent- and temperature-dependent dynamic behavior of anions occupying the central and the two outer pockets of a self-assembled, interpenetrated double cage is presented. Addition of two equivalents of solid AgCl led to exchange of the BF4− ions in the outer pockets by chloride (see figure). NOE data shows that the allosteric binding is accompanied by compression along and torsion around the Pd4 axis.
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