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Prof. Dr. Meilin Wei, Xiaoxiang Wang and Dr. Xianying Duan Crystal Structures and Proton Conductivities of a MOF and Two POM–MOF Composites Based on CuII Ions and 2,2′-Bipyridyl-3,3′-dicarboxylic Acid Chemistry - A European Journal 19

Version of Record online: 13 DEC 2012 | DOI: 10.1002/chem.201203154

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MOF connections: Three types of proton carriers are assembled in 1D hydrophilic channels of 3D metal–organic frameworks (MOFs) with two traditional but distinct building blocks, the metal N-heterocyclic multi-carboxylic acid frameworks and polyoxometalates (POMs), for the first time (see figure). These ordered poly-POM–MOFs show good proton conductivity across a wide range of temperature and relative humidity (RH). They could be models to provide valuable points for establishing structure–activity relationships.

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