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Dinesh Nath and Prof. Fraser F. Fleming Sulfinylnitriles: Sulfinyl–Metal Exchange–Alkylation Strategies Chemistry - A European Journal 19

Version of Record online: 23 DEC 2012 | DOI: 10.1002/chem.201203174

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Sulfinyl–metal exchange: Organometallic addition to sulfinylnitriles triggers a facile exchange route to C- or N-metalated nitriles (see scheme). Alkylations afford quaternary, tertiary, and alkenenitriles even in the presence of carbonyl functionality and highly acidic protons.

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