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Dr. Loránd Kiss, Maria Cherepanova, Dr. Enikő Forró and Prof. Ferenc Fülöp A New Access Route to Functionalized Cispentacins from Norbornene β-Amino Acids Chemistry - A European Journal 19

Version of Record online: 19 DEC 2012 | DOI: 10.1002/chem.201203183

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Ringing the changes: An efficient and simple new stereocontrolled access route to novel disubstituted cispentacin derivatives with multiple stereogenic centers from norbornene β-lactam has been developed (see scheme). The synthesis involves olefinic-bond functionalization by dihydroxylation followed by oxidative ring cleavage and transformation of the dialdehyde intermediate through a Wittig reaction.

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