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Dr. Maximilian N. Kopylovich, Dr. Archana Mizar, Dr. M. Fátima C. Guedes da Silva, Dr. Tatiana C. O. Mac Leod, Dr. Kamran T. Mahmudov and Prof. Armando J. L. Pombeiro Template Syntheses of Copper(II) Complexes from Arylhydrazones of Malononitrile and their Catalytic Activity towards Alcohol Oxidations and the Nitroaldol Reaction: Hydrogen Bond-Assisted Ligand Liberation and E/Z Isomerisation Chemistry - A European Journal 19

Version of Record online: 23 NOV 2012 | DOI: 10.1002/chem.201203254

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An effective assistant: CuII complexes containing arylhydrazones from methylene-active nitriles are effective catalysts and appear to act as suitable Lewis acids for the unprecedented possibility of a resonance-assisted hydrogen bond (RAHB)/coordination-controlled E/Z isomeric transition (see scheme).

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