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Eva Wirnhier, Maria B. Mesch, Prof. Dr. Jürgen Senker and Prof. Dr. Wolfgang Schnick Formation and Characterization of Melam, Melam Hydrate, and a Melam–Melem Adduct Chemistry - A European Journal 19

Version of Record online: 19 DEC 2012 | DOI: 10.1002/chem.201203340

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You're twisting my melam, man: Solvothermal reactions opened the door to the synthesis not only of bulk melam, [C3N3(NH2)2]2NH, but also of further crystalline intermediates in the carbon nitride condensation process. Whereas the formation of melam and a melam–melem adduct benefited from slower reaction kinetics, single crystals of melam hydrate are formed under hydrothermal conditions (see scheme).

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