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Helen Y. Playford, Dr. Alex C. Hannon, Dr. Emma R. Barney and Prof. Richard I. Walton Structures of Uncharacterised Polymorphs of Gallium Oxide from Total Neutron Diffraction Chemistry - A European Journal 19

Version of Record online: 10 JAN 2013 | DOI: 10.1002/chem.201203359

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To morph or not to morph? Three polymorphs of Ga2O3 with inherently disordered crystal structures and a gallium oxyhydroxide have structures based on close-packed oxide layers with partial filling of octahedral (circles) and tetrahedral (squares) interstitial sites. The relationship between these materials is reported, along with synthetic routes to these apparently simple solids that have potential in a variety of applications.

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