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Cristina García-Simón, Marc Garcia-Borràs, Dr. Laura Gómez, Dr. Isaac Garcia-Bosch, Dr. Sílvia Osuna, Prof. Marcel Swart, Dr. Josep M. Luis, Prof. Concepció Rovira, Prof. Manuel Almeida, Dr. Inhar Imaz, Prof. Daniel Maspoch, Dr. Miquel Costas and Dr. Xavi Ribas Self-Assembled Tetragonal Prismatic Molecular Cage Highly Selective for Anionic π Guests Chemistry - A European Journal 19

Version of Record online: 4 DEC 2012 | DOI: 10.1002/chem.201203376

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Host–guest in a nanocage: A Pd-carboxylate self-assembled nanocage with two porphyrin moieties has been spectroscopically and structurally characterized, and shows very high affinity for anionic π-guest molecules (see figure). The subtle parameters controlling the host–guest interaction are widely discussed by means of spectroscopic and computational experiments, and fine tuning of the physical properties of the guest has been achieved.

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