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Juan Xiao, Yuan Wu, Mian Li, Bao-Yu Liu, Prof. Dr. Xiao-Chun Huang and Prof. Dr. Dan Li Crystalline Structural Intermediates of a Breathing Metal–Organic Framework That Functions as a Luminescent Sensor and Gas Reservoir Chemistry - A European Journal 19

Version of Record online: 4 JAN 2013 | DOI: 10.1002/chem.201203515

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A rod-packing, breathing MOF (1), with two crystalline structural intermediates (1 a and 1 b; H2btca=benzotriazole-5-carboxylic acid) has been investigated. An underlying net approach for analyzing possible breathing MOFs, and a set of geometric parameters that can quantitatively describe such a breathing structural feature, are suggested. The 3D luminescent MOF is a promising candidate for specific sensors with exceptional sorption capacity.

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