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Dr. Bo Liu, Dr. Thierry Roisnel, Prof. Dr. Jean-François Carpentier and Dr. Yann Sarazin Cyclohydroamination of Aminoalkenes Catalyzed by Disilazide Alkaline-Earth Metal Complexes: Reactivity Patterns and Deactivation Pathways Chemistry - A European Journal 19

Version of Record online: 10 JAN 2013 | DOI: 10.1002/chem.201203562

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Playing a role: Phenolate and β-diketiminate disilazide complexes of the large alkaline-earth metals (Ca, Sr, and Ba) have been employed as competent catalysts for the cyclohydroamination of terminal aminoalkenes (see scheme). Trends regarding the catalytic activity of these complexes have been established and allow the discrimination between metal, ligand framework, and amido groups. A specific deactivation pathway has been identified, and several model compounds have been used for stoichiometric investigations.

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