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Dr. Caroline Clavel, Dr. Camille Romuald, Emile Brabet and Dr. Frédéric Coutrot A pH-Sensitive Lasso-Based Rotaxane Molecular Switch Chemistry - A European Journal 19

Version of Record online: 23 JAN 2013 | DOI: 10.1002/chem.201203597

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Molecular lasso: The synthesis of a [1]rotaxane molecular switch has been realized by self-entanglement of a hermaphroditic molecule. This is composed of an anilinium template (see figure, green ball) on a molecular tail, which is linked to a BMP25C8 macrocyclic head (red wheel). The trapping of the structure could be achieved by using triazolium (pink ball) as a molecular station and gate at the same time. A variation in pH triggers the tightening and loosening of the lasso.

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