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Dr. Asamanjoy Bhunia, Meike A. Gotthardt, Munendra Yadav, Dr. Michael T. Gamer, Dr. Andreas Eichhöfer, Dr. Wolfgang Kleist and Prof. Dr. Peter W. Roesky Salen-Based Coordination Polymers of Manganese and the Rare-Earth Elements: Synthesis and Catalytic Aerobic Epoxidation of Olefins Chemistry - A European Journal 19

Version of Record online: 28 DEC 2012 | DOI: 10.1002/chem.201203636

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Coordination polymer catalysts: A number of manganese- and lanthanide-containing 1D coordination polymers have been synthesized, in which the manganese atoms are in a salen-type scaffold (see figure; salen=N,N′-bis(4-carboxysalicylidene)ethylenediamine). The manganese–gadolinium compound was used as a catalyst in the liquid-phase epoxidation of trans-stilbene with molecular oxygen, which resulted in the formation of stilbene oxide.

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