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Jakub Olchowka, Clément Falaise, Dr. Christophe Volkringer, Dr. Natacha Henry and Dr. Thierry Loiseau Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid-State Topotactic Transformation upon Dehydration Chemistry - A European Journal 19

Version of Record online: 23 DEC 2012 | DOI: 10.1002/chem.201203748

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As strong as an oxo bridge: A series of UO22+[BOND]Cu2+ polycarboxylates with characteristic heterometallic bridging oxo groups (U[DOUBLE BOND]O[BOND]Cu) were synthesized; dehydration induced atomic rearrangement with the stabilization of a crystalline anhydrous form (see scheme).

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