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Dr. Zi-Jian Yao, Dr. Yue-Jian Lin, Dr. Zhen-Hua Li and Prof. Dr. Guo-Xin Jin C[BOND]C Bond Cleavage of Zwitterionic Carboranes Promoted by a Half-Sandwich Iridium(III) Complex Chemistry - A European Journal 19

Article first published online: 7 JAN 2013 | DOI: 10.1002/chem.201203850

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Open-and-shut case: The cage C[BOND]C bond cleavage of monosubstituted carborane derivatives at room temperature has now been achieved. This approach, which is facilitated by half-sandwich complexes, provides a facile and direct synthesis of pseudocloso metallacarboranes (see scheme; dots indicate carbon atoms).

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